WebJun 16, 2009 · Dinuclear metal complexes, especially (p-cymene)ruthenium dichloride dimer {[RuCl 2 (p-cymene)] 2}, have been found to exhibit high catalytic performance for the dehydrosilylation of various kinds of carboxylic acids and alcohols.The dehydrosilylation with [RuCl 2 (p-cymene)] 2 proceeded efficiently with only one equivalent of silane with …
Dichloro (p-cymene)ruthenium (II) Dimer 52462-29-0 TCI …
(Cymene)ruthenium dichloride dimer is the organometallic compound with the formula [(cymene)RuCl2]2. This red-coloured, diamagnetic solid is a reagent in organometallic chemistry and homogeneous catalysis. The complex is structurally similar to (benzene)ruthenium dichloride dimer. See more The dimer is prepared by the reaction of the phellandrene with hydrated ruthenium trichloride. At high temperatures, [(cymene)RuCl2]2 exchanges with other arenes: [(cymene)RuCl2]2 … See more Treatment of [(cymene)RuCl2]2 with the chelating ligand TsDPENH gives (cymene)Ru(TsDPEN-H), a catalyst for asymmetric transfer hydrogenation. [(cymene)RuCl2]2 … See more WebSep 3, 2013 · Request PDF Efficient and Rapid Synthesis of Chlorido-Bridged Half-Sandwich Complexes of Ruthenium, Rhodium, and Iridium by Microwave Heating The dinuclear complexes [(p-cymene)RuCl2](2) and ... broomfield colorado city and county
Dichloro(p-cymene)ruthenium(II) dimer, 98%, Thermo Scientific …
WebApr 15, 2013 · Graphical abstract. The heterodinuclear complexes [((6-p-MeC 6 H 4 Pr i)RuCl 2 (Ph 2 PfcCONHRCO 2 Me-(P)] have been synthesized from p-cymene ruthenium dichloride dimer and phosphinoferrocene ligands bearing carboxamide substituents derived from amino acids and studied for their in vitro anticancer activity towards human … WebDichloro(p-cymene)ruthenium(II) dimer C20H28Cl4Ru2 CID 10908223 - structure, chemical names, physical and chemical properties, classification, patents, literature, … Webcomplexes starting from the dichloro(p-cymene)ruthenium(II) dimer [(η6-p-MeC 6 H 4 Pri)Ru(µ 2-Cl)Cl] 2 and to modify, where necessary, the existing synthetic route to (i) increase the yields, (ii) reduce the overall reaction time (currently reflux in EtOH, 18h), and to (iii) synthesize novel trithiolato complexes. To this broomfield colorado fire evacuation